Hi TMzethar, it's a F4-423 running 6.0.648 now (610 when I opened the post). The extra share started showing up after a reboot, not even after an update, so I'm not sure what would have damaged it. Is there a guide on how to remove the internal boot drive? I don't recall seeing it when I installed the additional RAM but I wasn't specifically looking for it. EDIT: never mind, found it at
https://youtu.be/5zz4netQZRc?feature=shared&t=164 
I'll do it as soon as I have some time to take it apart.
The content of the share seems fine however (typical stuff one would expect from a linux boot disk), it's just that for some reason TNAS is not ignoring it and shows it as an external disk.
Regarding ps2022igwxuxkn, I can confirm that is indeed the NAS:
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octavarium:~ jollino$ smbutil lookup ps2022igwxuxkn
Got response from 192.168.0.50
IP address of ps2022igwxuxkn: 192.168.0.50
That is the the correct IP and I actually access its shares through that weird name:
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octavarium:~ jollino$ smbutil view //ps2022igwxuxkn
Password for ps2022igwxuxkn:
Share Type Comments
-------------------------------
TimeMachine Disk
IPC$ Pipe IPC Service (Supernova)
jollino Disk Home Directories
usbshare_sde1 Disk
4 shares listed
This also came up out of nowhere a few days ago. I also haven't installed any apps or anything weird. I did notice, AFTER seeing this show up on the network, that my Samba settings had been reset to default (including disabling the custom ones).
Also note that the 'ps2022igwxuxkn' instance is accessible from other devices as well, not just my main Mac.
I haven't tried rebooting yet, let me know if you want me to get any specific logs before I do.