Having set the LAN addresses I created the Fixed IP Bond, following the "suggested" (and logical) fixed LAN address of LAN1 for the BOND. When I susequently looked at TNAS-PC I noticed something odd. The BOND was using the LAN1 address but had picked up the LAN2 MAC address., (Note the MAC address is not shown in the Fixed IP setting on NAS for BOND IP.)
I ran 'ifconfig' on both NAS to confirm what I was seeing (LAN1 = eth0 and LAN2 = eth1)
[What you cannot see in the attachment are the details shown in TNAS-PC changing as they switch from LAN to BOND display and back again.]
I rearranged the IP assignment on the LAN adapters and this appears to have sorted things out into a more 'sane' (?) arrangement, but with the BOND showing as allocated to LAN2 in both cases.
Is there any logic in how interfaces are allocated to LAGG/Bond? Does Interface Servicing order have any effect?

